And our heat of reaction or enthalpy of reaction is defined as the enthalpy at constant pressure. 我们的反应热,或反映,的焓被定义为恒压,等温。
The former includes the calculation of reaction free enthalpy, equilibrium constants, maximum output, gaseous phase partial pressure and theoretical decomposition voltage of molten salt electrolysis. 前者包括反应自由焓、平衡常数、最大产量、气相分压以及熔盐电解理论分解电压的计算;
The extraction constant of uranium ( VI) with pyridines and the reaction enthalpy were calculated. 求得萃取硝酸铀酰过程的平衡常数及反应的热力学函数。
A new calculation method for chemical reaction enthalpy 介绍一种计算化学反应焓的新方法
Except reaction temperature, all the other reaction conditions could affect the structure of production, the intercalation process is controlled by enthalpy. 除反应温度外,其它反应条件的变化均会影响插层产物的结构,插层反应为焓驱动过程。
On the basis of characteristic of the state function, a formula has been derived by which tile △ G~ o of a chemical reaction can be calculated from the standard forma-tion free enthalpy. 并根据状态函数的特性,导出了从反应物及产物的标准生成自由焓计算化学反应△G°的公式。
The effect of temperature on the reaction was studied through thermodynamics, and the change of entropy, enthalpy and free energy of the reaction were calculated. 采用热力学方法研究了温度对包合反应的影响,计算了包合过程的熵变、焓变及自由能变化;
The results of those reactions show that the reaction activation energy and reaction enthalpy are reduced compared with the reaction in gas phase, indicating the reaction take place easily with the cooperation of water molecules and hydroxyl anion. 结果表明,与气相反应相比,在协同作用下,硫脲氧化反应活化能和反应焓降低了,反应更容易进行。
Thermodynamic analysis of the methanol to propylene reaction has been carried out. For each reaction enthalpy and Gibbs free energy at varying temperatures were presented. 本文对MTP反应体系进行了热力学分析,计算了各反应在不同温度下的反应焓变和吉布斯自由能变。
The results show the reactions of CV and AOT both in water/ AOT/ isooctane microemulsion and in water/ AOT/ decane microemulsion are endothermic and entropy promoting, and the effect of entropy of the association reaction is larger than the effect of enthalpy. 结果表明在水/AOT/异辛烷微乳液和水/AOT/正癸烷微乳液中CV和AOT的缔合反应均为吸热且熵驱动的反应,缔合反应的熵效应大于焓效应。
Then comparing the variety of different free radical spin trapping agents 'thermodynamic energy of the spin adduct, the reaction enthalpy is to determine a more stable structure among spin trapping agents, which is validated through experiments. 2. 并通过比较各种自旋捕捉剂不同自由基自旋加合物的热力学能量,反应焓变,生成热,确定了较稳定的自旋捕捉剂结构,并通过实验验证了这种结构的稳定性。